Unexpected products from the reaction of alkynylstannanes with 9-borabicyclo[3.3.1]nonane

Autor:	Christoph Bihlmayer, Bernd Wrackmeyer
Rok vydání:	1981
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Hydroboration chemistry Alkene Molecular Medicine chemistry.chemical_element Organic chemistry Nonane Boron 9-Borabicyclo[3.3.1]nonane
Zdroj:	Journal of the Chemical Society, Chemical Communications. :1093
ISSN:	0022-4936
DOI:	10.1039/c39810001093
Popis:	The reaction of 9-borabicyclo[3.3.1]nonane with alkynyltrimethylstannanes (Me3Sn–CC–R) yields a new alkene (R = But) and new allenes (R = Me3Si or Me3Sn); the formation of both types of compound is not consistent with hydroboration but involves exchange reactions, alkynyl borate intermediates, and organoboration.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2482680f85a98da6e8139f509e22d461 https://doi.org/10.1039/c39810001093 Zobrazit plný text záznamu