Kinetics of hydrogen peroxide-chlorate reaction in the formation of chlorine dioxide

Autor:	W. R. Ernst, M. Fazlul Hoq, Joel Tenney, Bhart Indu, Shelley Carr, Michael Burke
Rok vydání:	1993
Předmět:	Chlorine dioxide Aqueous solution Chemistry General Chemical Engineering Chlorate Inorganic chemistry Sulfuric acid General Chemistry Industrial and Manufacturing Engineering Reaction rate chemistry.chemical_compound Acidity function Hydrogen peroxide Sodium chlorate
Zdroj:	Industrial & Engineering Chemistry Research. 32:1449-1456
ISSN:	1520-5045 0888-5885
DOI:	10.1021/ie00019a020
Popis:	This paper reports and discusses an experimental prrogram that investigates chlorine dioxide formation by reduction of sodium chlorate with hydrogen peroxide in aqueous sulfuric acid. The rate of reaction was studied in both batch and well-mixed reactors over ranges of temperature and reactant concentrations which bracket conditions of commercial interest. The rate data were correlated by a power law model in which an acidity function H - was used to characterize the acidity of sulfuric acid.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::24791249bf1458d1a4a68f3553f8f4cd https://doi.org/10.1021/ie00019a020 Zobrazit plný text záznamu