[Bmmim]6[In10Se16Cl4]·(MIm)2: an organic-ligand free discrete T3 cluster for efficient hydrogen evolution under visible light irradiation

Autor:	Jian-Ce Jin, Yanqi Wang, Jian-Rong Li, Ji-Long Li, Xiao-Ying Huang, Qianqian Hu
Rok vydání:	2020
Předmět:	Materials science Chemical substance Dimethyl sulfoxide Ligand chemistry.chemical_element Photochemistry Inorganic Chemistry chemistry.chemical_compound chemistry Selenide Photocatalysis Cluster (physics) Science technology and society Indium
Zdroj:	Dalton Transactions. 49:5020-5023
ISSN:	1477-9234 1477-9226
DOI:	10.1039/d0dt00013b
Popis:	An indium selenide [Bmmim]6[In10Se16Cl4]·(MIm)2 (Bmmim = 1-butyl-2,3-dimethylimidazolium, MIm = 1-methylimidazole) cluster has been synthesized and characterized. The discrete T3 cluster could be stably dispersed in dimethyl sulfoxide, exhibiting photocatalytic hydrogen evolution activity at least six times that of the pristine in the solid state due to the exposure of more active sites.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2462c875dd59a597af1ecee2e3d44eda https://doi.org/10.1039/d0dt00013b Zobrazit plný text záznamu