Synthesis of quinolyl-substituted 4,7-phenanthrolines
Autor: | K. N. Gusak, N. S. Kozlov, V. A. Serzhanina |
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Rok vydání: | 1990 |
Předmět: | |
Zdroj: | Chemistry of Heterocyclic Compounds. 26:664-668 |
ISSN: | 1573-8353 0009-3122 |
Popis: | 1-(2-Quinolyl)-3-aryl-4,7-phenanthrolines were synthesized by reacting arylidene-6-quinolylamines with 2-acetylqidnoline in n-butanol in the presence of hydrochloric acid. It was found that the formation of the 4,7-phenanthroline ring is preceded by the stage of formation of an intermediate aminoketone, 1-(2-quinolyl)-3-phenyl-3-(6-quinolylamino)propan-1-one. The IR, UV, PMR, and mass spectra of the synthesized compounds are discussed. |
Databáze: | OpenAIRE |
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