Synthesis of quinolyl-substituted 4,7-phenanthrolines

Autor: K. N. Gusak, N. S. Kozlov, V. A. Serzhanina
Rok vydání: 1990
Předmět:
Zdroj: Chemistry of Heterocyclic Compounds. 26:664-668
ISSN: 1573-8353
0009-3122
Popis: 1-(2-Quinolyl)-3-aryl-4,7-phenanthrolines were synthesized by reacting arylidene-6-quinolylamines with 2-acetylqidnoline in n-butanol in the presence of hydrochloric acid. It was found that the formation of the 4,7-phenanthroline ring is preceded by the stage of formation of an intermediate aminoketone, 1-(2-quinolyl)-3-phenyl-3-(6-quinolylamino)propan-1-one. The IR, UV, PMR, and mass spectra of the synthesized compounds are discussed.
Databáze: OpenAIRE