The influence of symmetry-restricted spin diffusion on the spin-lattice relaxation of molecular groups in solids
Autor: | J. Smidt, S. Emid, R. J. Baarda, R. A. Wind |
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Rok vydání: | 1978 |
Předmět: | |
Zdroj: | Physica B+C. 93:327-343 |
ISSN: | 0378-4363 |
DOI: | 10.1016/0378-4363(78)90022-0 |
Popis: | The influence of symmetry-restricted spin diffusion on the spin-lattice relaxation of rapidly reorienting molecular groups in solids is considered. Each group consists of three identical spin-12 nuclei at the corners of an equilateral triangle. First, the spin-lattice relaxation of isolated three-spin systems is considered. Then symmetry-restricted spin diffusion is treated and its influence on the spin-lattice relaxation in solids is discussed. The resulting coupled spin-lattice relaxation equations explain phenomena like non-exponential relaxations in solids. Previous works concerning the spin-lattice relaxation in the symmetry-restricted spin diffusion model are discussed briefly. |
Databáze: | OpenAIRE |
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