1,4-Cyclohexadiene with Pd/C as a rapid, safe transfer hydrogenation system with microwave heating

Autor: Brian T. Gregg, John F. Quinn, Kathryn C. Golden, Dana A. Razzano
Rok vydání: 2008
Předmět:
Zdroj: Tetrahedron Letters. 49:6137-6140
ISSN: 0040-4039
Popis: A method for the rapid, safe hydrogenation of alkenes and deprotection of benzyl ethers and carboxybenzyl amides is described using catalytic transfer hydrogenation under microwave heating conditions. Commonly available Pd/C catalyst is extremely effective with 1,4-cyclohexadiene as the hydrogen transfer source. In general, the reactions are complete within five minutes at 100 °C.
Databáze: OpenAIRE