Thermodynamic data interpretation of the ion association process in mixed solvents
Autor: | Yu. Ya. Fialkov, V. L. Chumak |
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Rok vydání: | 2000 |
Předmět: |
Chemistry
Component (thermodynamics) Dielectric permittivity Binary number Thermodynamics Data interpretation Electrolyte Ion-association Condensed Matter Physics Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials Condensed Matter::Soft Condensed Matter Solvent Scientific method Materials Chemistry Physics::Chemical Physics Physical and Theoretical Chemistry Spectroscopy |
Zdroj: | Journal of Molecular Liquids. 84:193-202 |
ISSN: | 0167-7322 |
DOI: | 10.1016/s0167-7322(99)00186-5 |
Popis: | Some approaches have been developed which allow to divide thermodynamic functions of the ion association processes in two components. The first component belongs to the process, the second one is caused by the temperature dependence of the dielectric permittivity of the solvent. The theory is confirmed by numerous examples which deal with the ion association process of different electrolytes in binary mixed solvents. |
Databáze: | OpenAIRE |
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