Mixed cobalt(III) complexes with aromatic amino acids and diamines. III
| Autor: | Goran A. Bogdanović, M.J. Malinar, Djenana U. Miodragović |
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| Rok vydání: | 2002 |
| Předmět: |
biology
Hydrogen bond Stereochemistry Diastereomer chemistry.chemical_element Ethylenediamine 02 engineering and technology General Medicine Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences General Biochemistry Genetics and Molecular Biology 3. Good health 0104 chemical sciences Crystallography chemistry.chemical_compound chemistry biology.protein Molecule 0210 nano-technology Hydrate Cobalt Organic anion |
| Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 58:m338-m340 |
| ISSN: | 0108-2701 |
| DOI: | 10.1107/s0108270102006728 |
| Popis: | The title compound, [Co(C9H10NO3)2(C2H8N2)]Cl·4H2O, is one of six possible diastereomers of the (1,2-diaminoethane)bis(S-tyrosinato)cobalt(III) complex. The cobalt(III) ion has an octahedral coordination, with three five-membered chelate rings which have deformed coordination angles and coordinated O atoms in trans positions. In comparison with the previously reported crystal structure of the Δ-C1-cis(O) diastereomer [Miodragovic et al. (2001). Enantiomer, 6, 299–308], the compound presented in this paper has more planar five-membered aminocarboxylate rings. Complex cations, chloride anions and water molecules of crystallization are linked together by a network of hydrogen bonds. The chloride anions lie approximately between two Co atoms and form hydrogen bonds with all coordinated NH2 groups. In the crystal structure, there is a weak intermolecular π⋯π interaction between the phenyl rings. |
| Databáze: | OpenAIRE |
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