A unique tetra-nuclear AgI–disulfoxide complex, {[Ag2(O,O-L)(μ-O-μ-(SO)-L)2(ClO4)]ClO4}2 (L=meso−1,2-bis(ethylsulfinyl)ethane) with unprecedented ligand coordination mode

Autor:	Ruo-Hua Zhang, Xian-He Bu, Jian-Rong Li
Rok vydání:	2005
Předmět:	Denticity biology Ligand Stereochemistry Chemistry Organic Chemistry Crystal structure biology.organism_classification Analytical Chemistry Ion Inorganic Chemistry Crystallography Octahedron Tetra Chelation Spectroscopy
Zdroj:	Journal of Molecular Structure. 737:23-27
ISSN:	0022-2860
DOI:	10.1016/j.molstruc.2004.10.004
Popis:	The self-assembly of a flexible disulfoxide ligand, meso-1,2-bis(ethylsulfinyl)ethane (L) with AgClO4 led to the formation of a novel tetra-nuclear complex, {[Ag2(O,O-L)(μ-O-μ-(SO)-L)2(ClO4)]ClO4}2, in which the AgI ions exhibit two kinds of coordination modes: trigonal–bipyramidal and octahedral, and the ligands take bidentate (O,O) chelating and tridentate μ-O-μ-(SO) bridging-chelating coordination modes. Such a ligand coordination mode is unprecedented in the metal-complexes of disulfoxides.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::23c6ddea5f86cc030f1619ce5eddecd2 https://doi.org/10.1016/j.molstruc.2004.10.004 Zobrazit plný text záznamu Full Text from ScienceDirect