ChemInform Abstract: Optimized Synthesis of Vinyl Ether Sugars and Vinyl Glycosides Through Transfer Vinylation Catalyzed by (4,7-Ph2-phen) Pd(OOCCF3)2

Autor: Marcel Schlaf, Sean Handerson, Martin Bosch
Rok vydání: 2009
Předmět:
Zdroj: ChemInform. 40
ISSN: 1522-2667
0931-7597
DOI: 10.1002/chin.200903200
Popis: Sugar vinyl ethers and vinyl glycosides are conveniently synthesized by catalytic transfer vinylation with butyl vinyl ether, which serves as both the solvent and source of vinyl. The air‐stable catalyst (4,7‐diphenyl‐1,10‐phenanthroline)Pd(OOCCF3)2 is prepared in situ from commercially available components.
Databáze: OpenAIRE