Kinetics of aquation of chloropentamminecobalt(III) perchlorate in ethylene glycol-water media

Autor:	Mohamed F. Amira, Mohamed T. Mohamed, Abdullah S. Babaqi, Salah S. Massoud
Rok vydání:	1988
Předmět:	Arrhenius equation Reaction mechanism Chemistry Inorganic chemistry Metals and Alloys Solvation Aquation Inorganic Chemistry Reaction rate Perchlorate chemistry.chemical_compound symbols.namesake Materials Chemistry symbols Solvent effects Ethylene glycol
Zdroj:	Transition Metal Chemistry. 13:201-204
ISSN:	1572-901X 0340-4285
Popis:	The aquation of chloropentamminecobalt(III) ion has been studied in ethylene glycol-water mixtures up to 80% by weight at five temperatures from 35 to 55°C. Specific solvent effects on the reaction rate and mechanism have been investigated and discussed. The validity of our previously proposed equations, correlating the specific reaction rate with the dielectric constant of the medium has been examined. The thermodynamic parameters of activation have been calculated and presented as evidence for the solvation effects and in support of the proposed reaction mechanism.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::23a432d2e8ee7ed3dc3458b630b6d81d https://doi.org/10.1007/bf01171325 Zobrazit plný text záznamu Full text from SpringerLink