Apparent anomalous behavior of polar substituents on the benzene ring in the regioselectivity of di-π-methane rearrangement of 5,6-benzo-2-azabicyclo[2.2.2]octadienones

Autor:	Ei-ichi Mano, Takachiyo Okuda, Masayuki Kuzuya, Masanao Ishikawa, Harold Hart
Rok vydání:	1981
Předmět:	Stereochemistry Organic Chemistry Substituent Regioselectivity chemistry.chemical_element Anomalous behavior Ring (chemistry) Biochemistry Methane chemistry.chemical_compound chemistry Drug Discovery Polar Benzene Carbon
Zdroj:	Tetrahedron Letters. 22:1613-1616
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(01)90391-0
Popis:	Polar substituent effects on the aromatic ring emerge in the regioselectivity of the di-π-methane rearrangement of the title compounds when they possess the structural feature of including the bridgehead carbon in a saturated ring; the importance of the environment at the bridgehead carbon is pointed out.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2398a00a392f3ec2446210d69d878911 https://doi.org/10.1016/s0040-4039(01)90391-0 Zobrazit plný text záznamu