Alignment Photoregulation of a Nematic Liquid Crystal by Surface Adsorption of Aminoalkylated Azobenzenes

Autor: Kunihiro Ichimura, Masahide Ueda, Kazuaki Kudo
Rok vydání: 1996
Předmět:
Zdroj: Israel Journal of Chemistry. 36:371-378
ISSN: 0021-2148
DOI: 10.1002/ijch.199600051
Popis: Adsorption behavior of azobenzenes having an aminoalkyl residue onto a silica surface is described. Immersion of a silica plate in a benzene solution of an aminoalkylated azobenzene resulted in efficient adsorption to form face-to-face aggregates which are converted into monomeric states by partial desorption. Silica plates adsorbing the azobenzene bearing an aminoalkyl residue were employed to achieve the surface-assisted photoregulation of alignment of a nematic liquid crystal between homeotropic and planar modes. Based on these observations, a convenient method to prepare command surfaces for the orientational photoregulation of liquid crystals was presented by filling a liquid crystal containing an aminoalkylated azobenzene into an empty cell composed of clear silica plates.
Databáze: OpenAIRE