Experimental and Computational Study on a Variety of Structural Motifs and Coordination Modes in Aluminium Complexes of Di(2-pyridyl)amides and -phosphanides

Autor:	Damien Moigno, Alexander Murso, Wolfgang Kiefer, Dietmar Stalke, Matthias Pfeiffer, Lepakshaiah Mahalakshmi
Rok vydání:	2002
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Stereochemistry Ligand Aluminium Amide chemistry.chemical_element Structural motif
Zdroj:	European Journal of Inorganic Chemistry. 2002:3222-3234
ISSN:	1099-0682 1434-1948
Popis:	The (2-Py)2N ligand shows much more conformational freedom than the (2-Py)2P anion in aluminium coordination. The two isomers [Al{(NPy)Py}3] (1a) and [Al{(NPy)Py}2(Py2N)] (1b) were isolated, the former containing exclusively cistrans ligands, and the latter cis-trans ligands together with a trans-trans ligand. The energy differences in the noncoordinated anions (2-Py)2E (E = N, P) were determined by computational methods to be low in the amide. While the N Al
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::23657cc38c5cf12189fa861e49a8e50d https://doi.org/10.1002/1099-0682(200212)2002:12<3222::aid-ejic3222>3.0.co Zobrazit plný text záznamu Plný text