Structural phase transitions in the cyano-elpasolite CS2NaCo(CN)6, a neutron diffraction study
| Autor: | H.-B Bürgi, Denis Sheptyakov, Dmitry Chernyshov |
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| Rok vydání: | 2004 |
| Předmět: |
Diffraction
Neutron powder diffraction Structural phase Phase transition Materials science Neutron diffraction Atmospheric temperature range Condensed Matter Physics Electronic Optical and Magnetic Materials Crystallography Nuclear magnetic resonance Phase (matter) Electrical and Electronic Engineering Powder diffraction |
| Zdroj: | Physica B: Condensed Matter. 350:E379-E382 |
| ISSN: | 0921-4526 |
| DOI: | 10.1016/j.physb.2004.03.101 |
| Popis: | We have studied the phase transformations in the cyano-elpasolite Cs 2 NaCo(CN) 6 by neutron powder diffraction in the temperature range 300–630 K. The temperature evolution of diffraction patterns clearly indicates two phase transitions at T 1 =500 K and T 2 =590 K. Detailed characterization of structural changes confirms the sequence of phase transitions proposed earlier (P2 1 /n↔P4/mnc↔Fm3 m) and provides, for the first time, a microscopic picture of the transformations of Cs 2 NaCo(CN) 6 . |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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