Dispersed fluorescence spectroscopy of jet-cooled DCO

Autor:	James R. Dunlop, Eric A. Rohlfing, Joseph D. Tobiason
Rok vydání:	1995
Předmět:	symbols.namesake Chemistry symbols General Physics and Astronomy Fermi resonance Physical and Theoretical Chemistry Atomic physics Hamiltonian (quantum mechanics) Fluorescence Spectral line Fluorescence spectroscopy
Zdroj:	Chemical Physics Letters. 235:268-276
ISSN:	0009-2614
Popis:	We obtain dispersed fluorescence (DF) spectra of jet-cooled DCO from three excited-state levels in the B 2 A′-X 2 A′ system. These spectra yield term energies and relative fluorescence intensities for 112 levels (mostly quasibound resonances) of DCO (X) over an energy range of 0–19000 cm −1 . We make zeroth-order, normal-mode vibrational assignments to 99 levels; however, their term energies are not well described by the customary (Dunham) expression due to extensive vibrational mixing and the weak CD bond. The use of an improved spectroscopic Hamiltonian that includes Fermi resonance and Darling-Dennison coupling terms is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::235e4ba08de2dcc69c1f875e473a9234 https://doi.org/10.1016/0009-2614(95)00102-a Zobrazit plný text záznamu Full Text from ScienceDirect