Double rearrangement in the pyrrolidine-1,2-oxide system leading to pentasubstituted pyrroles

Autor:	André Dehnel, Jolanta M. Kanabus-Kaminska
Rok vydání:	1987
Předmět:	chemistry.chemical_compound Acid catalysis Bicyclic molecule Stereochemistry Chemistry Acid catalyzed Organic Chemistry Drug Discovery Oxide Organic chemistry Biochemistry Pyrrolidine
Zdroj:	Tetrahedron Letters. 28:3907-3910
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)96417-7
Popis:	Acid catalyzed double rearrangement of the ethyl 6-oxa-2,2, 4,4-tetramethyl-1-azabicyclo[3,1,0]hexane-3-carboxylate leading to ethyl 1,2,4,5-tetramethyl-pyrrole-3-carboxylate is proposed on the basis of identification of the intermediate ethyl 5-hydroxy-1,2,4,4-tetramethylpyrroline-3-carboxylate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::23561496d4ac0a10e0ed452825967315 https://doi.org/10.1016/s0040-4039(00)96417-7 Zobrazit plný text záznamu