A pulse radiolysis study of electron solvation in methanol-2-methyltetrahydrofuran mixtures above and below the glass transition temperature

Autor:	S.J. Atherton, B.M. Hoey, J.H. Baxendale
Rok vydání:	1984
Předmět:	chemistry.chemical_compound Reaction mechanism Radiation chemistry 2-Methyltetrahydrofuran Radiolysis Benzophenone Solvation Physical chemistry Methanol Electron Photochemistry Glass transition
Zdroj:	Radiation Physics and Chemistry (1977). 23:13-18
ISSN:	0146-5724
Popis:	Observations of the solvation of electrons by methanol in methanol-2-methyltetrahydrofuran (MTHF) mixtures have been made at temperatures above and below the glass transition temperature. Results above the glass transition temperature are explained by a normal diffusion mechanism for solvation, whereas those at 77K are explained by electron tunnelling to methanol clusters. Observations of the solvation of benzophenone anions in these solutions support the above mechanisms.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::23415bb57b08583e3fcb20da4cb10fa8 https://doi.org/10.1016/0146-5724(84)90084-0 Zobrazit plný text záznamu