Effect of External Acidity of Mordenite-Supported Catalysts on the 2,2-Dimethylbutane Content in Hydroisomerization Products of n-Hexane

Autor: F. M. Bobonich, Yu. V. Belokopytov, V. V. Bobik
Rok vydání: 2003
Předmět:
Zdroj: Theoretical and Experimental Chemistry. 39:364-368
ISSN: 0040-5760
DOI: 10.1023/b:thec.0000013989.04033.e1
Popis: We have used potentiometric titration with tetrabutylammonium hydroxide to determine the acid center content on the outer surface of dealuminated natural and synthetic mordenites. We have established a symbatic relationship between the 2,2-dimethylbutane content in the hydroisomerization products of n-hexane on dealuminated palladium-containing mordenites and the number of their external acid centers. We have studied the possibility of partial deactivation of such centers during ion-exchange deposition of palladium on the catalysts, using a tetraammine palladium solution.
Databáze: OpenAIRE