Eclipsed cofacial dimers of metal complexes containing d7–d7and d8–d8metal bonds. Crystal structure of bis[bis{(phenanthrene-9,10-diamin)ylato}cobalt(II)] and bis[{(2,3-dicyanoethenediamin)ylato}dicarbonylrhodium(I)]

Autor:	Shuenn-Shing Chern, Ming-Chi Liaw, Shie-Ming Peng
Rok vydání:	1993
Předmět:	Eclipsed conformation Stereochemistry Imine chemistry.chemical_element Crystal structure Metal chemistry.chemical_compound Crystallography chemistry visual_art Diamine X-ray crystallography visual_art.visual_art_medium Molecular Medicine Molecule Cobalt
Zdroj:	J. Chem. Soc., Chem. Commun.. :359-361
ISSN:	0022-4936
DOI:	10.1039/c39930000359
Popis:	Two novel crystal structures containing the eclipsed conformation of diaminylato type ligands and metal–metal bonds are described; bis[bis{(phenanthrene-9,10-diamin)ylato}cobalt(II)] contains a CoII–CoII bond [2.689(1)A] and two δ bonds between two pairs of parallel (phenanthrene-9,10-diamin)ylato ligands and bis[{(2,3-dicyanoethenediamin)ylato}dicarbonylrhodium(I)] contains a RhI–RhI bond [2.833(2)A] and one δ bond between a pair of parallel (2,3-dicyanoethenediamin)ylato ligands.
Databáze:	OpenAIRE
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