Novel high phosphorus content phosphaphenanthrene-based efficient flame retardant additives for lithium-ion battery
| Autor: | Yujian Yu, Yufen Zhao, Xiao Li, Xiangming Feng, Jinyun Zheng |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
Thermogravimetric analysis
Materials science Phosphorus Inorganic chemistry chemistry.chemical_element Nuclear magnetic resonance spectroscopy Carbon-13 NMR Condensed Matter Physics humanities Lithium-ion battery Differential scanning calorimetry chemistry Chemical engineering Thermal stability Physical and Theoretical Chemistry Fire retardant |
| Zdroj: | Journal of Thermal Analysis and Calorimetry. 117:319-324 |
| ISSN: | 1588-2926 1388-6150 |
| DOI: | 10.1007/s10973-014-3679-5 |
| Popis: | The novel phosphate derivatives of phosphaphenanthrene with high-density phosphorus were synthesized and used as flame retardant additives for Li-ion batteries. The structures of compounds were characterized by 1H NMR, 13C NMR, 31P NMR, FT-IR, and HR-MS. The excellent thermal stability of compounds was ascertained by thermogravimetric analysis and differential scanning calorimetry. The compounds were added to conventional electrolytes as flame retardant additives and evaluated their ionic conductivity, electrochemical stability, self-extinguishing properties, and combustion performance. The results showed that the compound containing higher phosphorus content has efficient flame retardant properties. |
| Databáze: | OpenAIRE |
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