Poly(hydroxy ether sulfonamides). A new class of epoxy-based thermoplastics
| Autor: | Anthony P. Haag, R. Garth Pews, Shari L. Kram, Chester E. Pawloski, Charles N. Brown, Jerry E. White |
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| Rok vydání: | 1996 |
| Předmět: |
chemistry.chemical_classification
Materials science Polymers and Plastics Organic Chemistry chemistry.chemical_element Ether Epoxy Polymer Ring-opening polymerization Oxygen Amorphous solid chemistry.chemical_compound chemistry visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Organic chemistry Relative humidity Thermal analysis |
| Zdroj: | Journal of Polymer Science Part A: Polymer Chemistry. 34:2967-2973 |
| ISSN: | 1099-0518 0887-624X |
| Popis: | Base-initiated polymerizations of N,′N-dimethyl-1,3-benzenedisulfonamide or other N,′N-dialkyldisulfonamides with various arylene-diglycidyl ethers afford a broad range of poly(hydroxy ether sulfonamides) (2). Polymers 2, which represent a new family of epoxy-based thermoplastics, are moldable, amorphous materials characterized by moderate Tg (58–127°C) and by good barrier to oxygen, reflected by oxygen transmission rates of 0.45–2.89 cc-mil/100 in2-atm (O2)-day at 234 °C and about 60% relative humidity. In addition to a discussion of how structural changes in the backbones of 2 influence their barrier properties, details of the synthesis, thermal analysis and mechanical evaluation of the polymers are described. © 1996 John Wiley & Sons, Inc. |
| Databáze: | OpenAIRE |
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