Electrochemical Dechlorination of 1,2,4-Trichlorobenzene Using a Reticulated Vitreous Carbon Electrode

Autor:	Bo-Young Lee, Ki-Jung Paeng, Chae-Yun Lim, Noseung Myung, Insook Rhee Paeng
Rok vydání:	2003
Předmět:	Electrolysis Working electrode Chemistry Inorganic chemistry chemistry.chemical_element Trichlorobenzene General Chemistry Electrochemistry law.invention Dichlorobenzene chemistry.chemical_compound law Electrode medicine 1 2 4-Trichlorobenzene Carbon medicine.drug
Zdroj:	Bulletin of the Korean Chemical Society. 24:1329-1332
ISSN:	0253-2964
DOI:	10.5012/bkcs.2003.24.9.1329
Popis:	Stepwise dechlorination of 1,2,4-trichlorobenzene was observed at a glassy carbon electrode in dimethylformamide containing 0.1 M tetraethylammonium perchlorate. Especially, dechlorination to dichlorobenzene and further to monochlorobenzene or benzene was successfully demonstrated with a porous reticulated vitreous carbon electrode. Electrochemical dechlorination of polychlorobenzenes employing a flow cell with a reticulated vitreous carbon working electrode is also described. Preliminary experiments with a flow cell showed that dechlorination of trichlorobenzene to dichlorobenzene was partially completed while dechlorination to benzene or monochlorobenzene was not successful, suggesting that a flow rate and electrolysis time should be further optimized for the complete electrolysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::227a71d6cf4c3587e3f299ab4503d9dc https://doi.org/10.5012/bkcs.2003.24.9.1329 Zobrazit plný text záznamu