Proton delivery through a dynamic 3D H-bond network constructed from dense hydroxyls for advanced ion-selective membranes
| Autor: | Ce Hao, Xiaoming Yan, Lei Hu, Yan Dai, Xuemei Wu, Gaohong He, Wenji Zheng, Li Gao |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
Proton Renewable Energy Sustainability and the Environment Hydrogen bond Vanadium chemistry.chemical_element 02 engineering and technology General Chemistry Permeation 021001 nanoscience & nanotechnology Flow battery Ion Membrane Chemical engineering chemistry Proton transport General Materials Science 0210 nano-technology |
| Zdroj: | Journal of Materials Chemistry A. 7:15137-15144 |
| ISSN: | 2050-7496 2050-7488 |
| Popis: | An advanced ion-selective membrane containing a dynamic hydroxyl-based 3D H-bond network is first proposed for improved efficiencies and stability in flow battery applications. The 3D H-bond network structure is constructed by the nanoscale aggregation of hydrophilic dense-hydroxyl side chains anchored to hydrophobic polybenzimidazole. This unique dynamic H-bond network creates proton transport highways as well as vanadium permeation barriers across the membrane, leading to an ultralow vanadium ion permeability ( |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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