Fluorine-containing?-sultones Communication 15. Alkyl fluorosulfates

Autor:	M. A. Belaventsev, G. A. Sokol'skii, U. L. Knunyants
Rok vydání:	1966
Předmět:	chemistry.chemical_classification Sulfonyl General method chemistry.chemical_element General Chemistry Sulfuryl chloride Sulfonyl chloride Medicinal chemistry Chloride chemistry.chemical_compound chemistry medicine Fluorine Organic chemistry Alkyl medicine.drug
Zdroj:	Bulletin of the Academy of Sciences, USSR Division of Chemical Science. 15:972-976
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00846050
Popis:	1. In the reactions of tetrafluoro-2-hydroxyethanesulfonicβ-sultone with methane sulfonyl chloride, with alkyl chlorosulfates, and with sulfuryl chloride trifluorovinyl chlorosulfate is formed together with the corresponding fluorosulfonyl compounds. 2. The reactions of fluorine-containingβ-sultones with alkyl chlorosulfates provide a general method for the preparation of previously inaccessible alkyl fluorosulfates. 3. The main functional peculiarity of alkyl fluorosulfates is their great alkylating power. 4. It was deduced that the fluorosulfonyloxy group has a refraction\(ROSO_2 F\) of 11.50.
Databáze:	OpenAIRE
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