A liposoluble cationic complex of Ru(II) based on 1,4,5,8-tetra-azaphenanthrene

Autor:	M. ‐L. Garcia Y Abeledo, R. Nasielski-Hinkens, J. Nasielski
Rok vydání:	2010
Předmět:	chemistry.chemical_classification biology Base (chemistry) Ligand Cationic polymerization General Chemistry biology.organism_classification Medicinal chemistry chemistry.chemical_compound Hydroxylamine chemistry Yield (chemistry) Diamine Tetra Organic chemistry Amination
Zdroj:	Bulletin des Sociétés Chimiques Belges. 97:743-750
ISSN:	0037-9646
Popis:	Reacting 2,2-dichlorododecanal with 1,2-diamino-4-nitrobenzene in dioxane in the presence of a base gives a 46% yield of 2-decyl-6-nitroquinoxaline, which after amination by hydroxylamine and reduction gave 5,6-diamino-2-decylquinoxaline. This diamine, again with 2,2-dichlorododecanal in dioxane and base, affords 2,6-didecyl- and 2,7-didecyl-1,4,5,8-tetraazaphenanthrene (2,7ddTAP); the latter ligand gives the hexane-soluble Ru(2,7ddTAP)3(PF6)2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2234caaca8fce4be89c95f5b41e1b96e https://doi.org/10.1002/bscb.19880971003 Zobrazit plný text záznamu