Enhancement Effect of Cetyltrimethylammonium Bromide on Electrochemical Determination of Chlorophenols using a Carbon Paste Electrode
| Autor: | Tahir Arbneshi, Arsim Maloku, Kurt Kalcher, Liridon Berisha, Granit Jashari |
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| Rok vydání: | 2020 |
| Předmět: |
Hydroquinone
010401 analytical chemistry 010402 general chemistry Electrochemistry 01 natural sciences 0104 chemical sciences Analytical Chemistry Pentachlorophenol Carbon paste electrode chemistry.chemical_compound chemistry Bromide Phenol Differential pulse voltammetry Cyclic voltammetry Nuclear chemistry |
| Zdroj: | Journal of Analytical Chemistry. 75:358-365 |
| ISSN: | 1608-3199 1061-9348 |
| DOI: | 10.1134/s1061934820030120 |
| Popis: | The electrochemical responses of chlorophenols can be effectively enhanced by using the surfactant cetyltrimethylammonium bromide (CTAB) in combination with a carbon paste electrode (CPE). The influence of CTAB on the electrochemical behavior of hydroquinone, phenol, 2-chlorophenol, 2,4-dichlorophenol, 2,4,6-trichlorophenol, p-chloro-m-cresol and pentachlorophenol at the CPE was investigated in the phosphate buffer solution (pH 7). The concentration of CTAB affecting the electrochemical reaction of phenols was examined and the optimal concentration was 0.2 mM. In this research we have applied electrochemical methods, such as cyclic voltammetry and differential pulse voltammetry (DPV). The CPE modified with CTAB in DPV increased signal intensity for chlorophenols by around 5 to 13 times and was successfully applied to determination of chlorophenols in soil samples. |
| Databáze: | OpenAIRE |
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