Two unprecedented aromatic guanidines supramolecular chains self-assembled by hydrogen bonding interaction

Autor:	Yunshen Zhang, Yichao Huang, Li Zhu, Kun Chen, Jiangwei Zhang, Jian Hao
Rok vydání:	2015
Předmět:	Hydrogen bond Chemistry Stereochemistry Organic Chemistry Supramolecular chemistry Ring (chemistry) Analytical Chemistry Self assembled Inorganic Chemistry Crystal Crystallography Helix Single crystal Spectroscopy Guanidine derivatives
Zdroj:	Journal of Molecular Structure. 1097:145-150
ISSN:	0022-2860
DOI:	10.1016/j.molstruc.2015.05.024
Popis:	Two aromatic guanidine derivatives, C6H5N = C(NHCy)2 (1), (n-TBA)C6H5NHC(NHCy)2Mo2O7 (2) (Cy = cyclohexyl), were synthetized with high yields. Both of them self-assembled into supramolecules via H-bond interactions. Single crystal XRD indicated that crystal 1 showed helix chains combining pseudo four-fold and pseudo six-fold symmetries, while crystal 2 presented ladder chains with alternate ring structures. In this paper, a novel way to design ladder-like supramolecular chains from helix chains was presented, using POMs (polyoxometalates) to provide protons to help assembly.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::21f3338a49b3678bc3bf1714fe68a94c https://doi.org/10.1016/j.molstruc.2015.05.024 Zobrazit plný text záznamu Full Text from ScienceDirect