Thegem-Diol Form of (py)2CO as a Ligand in Cobalt(II) Carboxylate Clusters: A Cubane Complex and a Novel Nonanuclear Species with a Vertex-Sharing Double Square Pyramidal Structure

Autor:	Evangelos G. Bakalbassis, Catherine P. Raptopoulou, Stavroula Dionyssopoulou, Aris Terzis, Spyros P. Perlepes, Alexandros Tsohos
Rok vydání:	1999
Předmět:	Ligand Stereochemistry Diol chemistry.chemical_element General Chemistry Catalysis Square pyramidal molecular geometry Crystallography chemistry.chemical_compound chemistry Square pyramid Cubane Pyridine Carboxylate Cobalt
Zdroj:	Angewandte Chemie International Edition. 38:983-985
ISSN:	1521-3773 1433-7851
DOI:	10.1002/(sici)1521-3773(19990401)38:7<983::aid-anie983>3.0.co;2-k
Popis:	A vertex-sharing double square pyramid of cobalt(II) ions (see picture) is present in the nonanuclear complex 1, obtained by treating cobalt acetate with 0.5 equivalents of (py2 )CO. The corresponding 1:1 reaction gave 2, which has a central core with a cubane structure. py=pyridine.
Databáze:	OpenAIRE
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