High-resolution near-infrared luminescence of mangenese(V) in tetrahedral oxo coordination

Autor:	Dirk Reinen, Hans U. Güdel, Christa Albrecht, Markus Herren
Rok vydání:	1991
Předmět:	chemistry.chemical_classification Photoluminescence Doping Inorganic chemistry Analytical chemistry General Physics and Astronomy chemistry.chemical_element Manganese chemistry Crystal field theory Impurity Physical and Theoretical Chemistry Luminescence Inorganic compound Order of magnitude
Zdroj:	Chemical Physics Letters. 183:98-102
ISSN:	0009-2614
DOI:	10.1016/0009-2614(91)85106-7
Popis:	Manganese(V)-doped crystals of Ba5(PO4)3Cl (apatite structure) and Ca2VO4Cl (spodiosite structure) exhibit highly resolved photoluminescence in the near-infrared. It is assigned to intraconfigurational 1Ea3A2 (Td notation) transitions, and the vibrational sideband structure is interpreted in terms of bending and stretching vibrations of the (MnO4)3− entity. In lightly doped samples of the apatite compound, both the intensity and the lifetime of the luminescence (τ10 K=0.41 ms) drops by an order of magnitude between 10 K and room temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::21bab6762553f546fb2d0af9d07b86ca https://doi.org/10.1016/0009-2614(91)85106-7 Zobrazit plný text záznamu