Two Unique Entangling CdII-Coordination Frameworks Constructed by Square Cd4-Building Blocks and Auxiliary N,N′-Donor Ligands

Autor: Peng Zhang, Dongsheng Li, Kun Zou, Zi-Fan Fang, Jun Zhao, Miao Du, Yi-Qiang Mu
Rok vydání: 2012
Předmět:
Zdroj: Crystal Growth & Design. 12:1697-1702
ISSN: 1528-7505
1528-7483
DOI: 10.1021/cg300036y
Popis: This work presents two unique entangled coordination polymers based on square Cd4-building blocks. Complex 1 represents the first example of 2D→ 3D parallel polycatenated architecture constructed from a 4·82-fes net, whereas complex 2 shows an unusual (3,4)-connected self- catenated network that can be viewed as the cross-linking of a 2D + 2D→3D inclined polycatenation.
Databáze: OpenAIRE