Tin oxide based dye-sensitized solid-state solar cells: surface passivation for suppression of recombination
| Autor: | G.R.R.A. Kumara, Kirthi Tennakone, B. Onwona-Agyeman, A. G. U. Perera, Chandana Sampath Kumara Ranasinghe, R.M.G. Rajapakse, E.N. Jayaweera |
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| Rok vydání: | 2015 |
| Předmět: |
Materials science
Passivation Magnesium Mechanical Engineering Inorganic chemistry chemistry.chemical_element Molar absorptivity Condensed Matter Physics Tin oxide chemistry.chemical_compound Chemical engineering chemistry Mechanics of Materials Indoline General Materials Science Crystallite Recombination Leakage (electronics) |
| Zdroj: | Materials Science in Semiconductor Processing. 40:890-895 |
| ISSN: | 1369-8001 |
| Popis: | Dye-sensitized solid-state solar cells based on SnO2 where the crystallite surface is passivated with ultrathin structures constituted of MgO, ZnO and CaO are examined using high extinction coefficient indoline dye D149 as the sensitizer. Results clearly demonstrate that surface passivation effectively suppress leakage of electrons from interconnected SnO2 crystallites preventing recombination with the hole transport substrate CuSCN. In the presence of passivating films of any type, the optimum efficiency occurred at nearly same SnO2 film thickness of 12 mu m. MgO passivated system at a MgO surface concentration of similar to 8 x 10(-9) g cm(-2) yielded the highest efficiency of 2.82% under standard measurements conditions using cells of active area 0.25 cm(2). (C) 2015 Elsevier Ltd. All rights reserved. |
| Databáze: | OpenAIRE |
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