Diode laser spectroscopy of the ν7a band of fluorobenzene
Autor: | María N. Sánchez, Silvia Calvo, Fernando Castaño, Francisco J. Basterretxea |
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Rok vydání: | 2010 |
Předmět: |
Jet (fluid)
Materials science Infrared Fluorobenzene Laser Atomic and Molecular Physics and Optics Spectral line law.invention chemistry.chemical_compound Nuclear magnetic resonance chemistry law Physical and Theoretical Chemistry Atomic physics Absorption (electromagnetic radiation) Spectroscopy Line (formation) Diode |
Zdroj: | Journal of Molecular Spectroscopy. 261:124-128 |
ISSN: | 0022-2852 |
DOI: | 10.1016/j.jms.2010.04.003 |
Popis: | The diode laser absorption infrared spectrum of fluorobenzene has been recorded near 1230 cm −1 after cooling the molecules in a supersonic pulsed jet. Spectral lines have been assigned to the ν 7a fundamental band. Transitions of J between 32 and 49 have been recorded, that show characteristic line groupings in the P branch. Analysis of the spectrum gives the vibrational band origin and rotational and centrifugal distortion constants of the molecule in the ν 7a = 1 state. |
Databáze: | OpenAIRE |
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