ChemInform Abstract: ISOMERIZATION OF CYCLOHEXENYL CATIONS

Autor: Lynne Craine, Dan Fărcaşiu
Rok vydání: 1977
Předmět:
Zdroj: Chemischer Informationsdienst. 8
ISSN: 0009-2975
DOI: 10.1002/chin.197701116
Popis: Contrary to the literature data, the cyclohexenyl cation (I) rearranges to the 1-methylcyclopentenyl cation (IV) in FSO3H-SbF5(4 : 1) at –20 °C; the rate of ring contraction is much slower than the published rate of intramolecular H/D scrambling for labelled (I).
Databáze: OpenAIRE