ChemInform Abstract: ISOMERIZATION OF CYCLOHEXENYL CATIONS
Autor: | Lynne Craine, Dan Fărcaşiu |
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Rok vydání: | 1977 |
Předmět: | |
Zdroj: | Chemischer Informationsdienst. 8 |
ISSN: | 0009-2975 |
DOI: | 10.1002/chin.197701116 |
Popis: | Contrary to the literature data, the cyclohexenyl cation (I) rearranges to the 1-methylcyclopentenyl cation (IV) in FSO3H-SbF5(4 : 1) at –20 °C; the rate of ring contraction is much slower than the published rate of intramolecular H/D scrambling for labelled (I). |
Databáze: | OpenAIRE |
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