Autor:	G. I. Khaikin, E. L. Protasova
Rok vydání:	2001
Předmět:	chemistry.chemical_compound Aqueous solution Reaction rate constant Chemistry Nitric acid Hydrazine Inorganic chemistry Radiolysis Hydrazoic acid chemistry.chemical_element Reactivity (chemistry) Physical and Theoretical Chemistry Nitrogen
Zdroj:	High Energy Chemistry. 35:219-223
ISSN:	0018-1439
Popis:	The rate constants of reactions of the NO3•radical with hydrazoic acid (7.6 × 106l mol–1s–1) and the hydrazonium ion (2.3 × 106l mol–1s–1) in 6 M nitric acid at 290 ± 2 K were measured by a pulse radiolysis technique. The reaction scheme was refined by the computer simulation of the γ-radiolysis of aqueous nitric acid solutions of hydrazine with the use of the measured rate constants and published data on the reactivity of intermediates. The results of computations were compared with experimental data on the continuous radiolytic degradation of hydrazine in aqueous 2 M nitric acid solutions at 313 K.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::216d2e18d3d2df6457b4e564a08ebe87 https://doi.org/10.1023/a:1017676326298 Zobrazit plný text záznamu Full text from SpringerLink