Europium-activated phosphor Ba3Lu2B6O15: Influence of isomorphic substitution on photoluminescence properties
| Autor: | Ilya E. Kolesnikov, Stanislav K. Filatov, Y.P. Biryukov, Alexey Povolotskiy, Anastasia Povolotckaia, Rimma S. Bubnova, O. Yu. Shorets |
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| Rok vydání: | 2021 |
| Předmět: |
010302 applied physics
Materials science Photoluminescence Process Chemistry and Technology Doping chemistry.chemical_element Phosphor 02 engineering and technology Crystal structure 021001 nanoscience & nanotechnology 01 natural sciences Lutetium Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry 0103 physical sciences Materials Chemistry Ceramics and Composites Physical chemistry Chromaticity 0210 nano-technology Luminescence Europium |
| Zdroj: | Ceramics International. 47:8030-8034 |
| ISSN: | 0272-8842 |
| DOI: | 10.1016/j.ceramint.2020.11.156 |
| Popis: | This work demonstrates the luminescent properties of Ba3Lu2B6O15 phosphors doped with Eu3+ ions for the first time. The Ba3(Lu1–xEux)2B6O15 (x = 0.01–0.375) phosphors have been prepared using a multi-step high-temperature solid-state synthesis. X-ray diffraction measurements verify the successful isomorphic substitution of the Lu3+ sites by the Eu3+ ions. The luminescence properties and its dependence on the crystal structure of Ba3(Lu1–xEux)2B6O15 have been reported in this work. There are two nonequivalent sites in this crystal structures occupied by lutetium, both of them can be consistently substituted by the Eu3+ ions. The highest emission intensity with quantum yield of 17% was demonstrated by Ba3(Lu0.82Eu0.18)2B6O15 powder. Increase of Eu3+ doping concentration leads to gradual change of chromaticity from violet to red. It was expected that Ba3(Lu1–xEux)2B6O15 phosphors can be used as a phosphor with predicted chromaticity under LED excitation. |
| Databáze: | OpenAIRE |
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