Polymers containing metal chelate units III. Binuclear copper(II) complex with salicyloylacrylamide immobilised on polytetrafluoroethylene and its use as a polymeric antifriction coating

Autor:	V.N. Sheinker, Igor E. Uflyand, A. D. Pomogailo, M. O. Gorbunova, A.S. Kuzharov
Rok vydání:	1990
Předmět:	chemistry.chemical_classification Polytetrafluoroethylene Ligand Inorganic chemistry General Engineering chemistry.chemical_element Polymer Copper chemistry.chemical_compound Thionyl chloride chemistry Polymerization Polymer chemistry Surface modification Acrylic acid
Zdroj:	Reactive Polymers. 13:145-151
ISSN:	0923-1137
DOI:	10.1016/0923-1137(90)90049-a
Popis:	A method of functionalization of a polytetrafluoroethylene (PTFE) surface by the gas phase graft (-g-) polymerization of acrylic acid (AA) with PTFE has been developed. A new macromolecular ligand PTFE-g-poly(salicyloylacrylamide) has been synthesized by the interaction of salicylamide with PTFE-g-PAA under the action of thionyl chloride. The macromolecular metal complex has been prepared by mixing a suspension of polymeric ligand with copper(II) acetate in alcohol. Its composition, IR spectrum and magnetic properties in the temperature range 80–300 K have been investigated. The immobilised binuclear complex was used in the production of antifriction self-lubricated coatings.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2159d3c8c9158474dcbccc2677c6b1b6 https://doi.org/10.1016/0923-1137(90)90049-a Zobrazit plný text záznamu