ChemInform Abstract: An Unusual Boron-Assisted Substitution in the Synthesis of α-Methoxylated Fatty Acids Isolated from Caribbean Sponges

Autor:	John A. Soderquist, Yernan Marrero, Izander Rosado
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Sponge chemistry biology Stereochemistry Spheciospongia chemistry.chemical_element Hydroxide General Medicine Boron biology.organism_classification Derivative (chemistry)
Zdroj:	ChemInform. 29
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199832277
Popis:	The Suzuki-Miyaura cross coupling of 4-bromo-1-butyl-9-BBN produces 4-hydroxybutyl products evidently arising from a boron-assisted hydroxide substitution. This process was utilized in the synthesis of (±)-2-methoxy-5Z-hexadecenoic acid methyl ester ( 1 ), a derivative of the phospholipids isolated from the Caribbean sponge, Spheciospongia cuspidifera.
Databáze:	OpenAIRE
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