Mechanism of acetylene and olefin insertion into palladium-carbon .sigma. bonds
| Autor: | Edward G. Samsel, Jack R. Norton |
|---|---|
| Rok vydání: | 1984 |
| Předmět: |
chemistry.chemical_classification
Olefin fiber Intramolecular reaction Stereochemistry chemistry.chemical_element General Chemistry Biochemistry Medicinal chemistry Catalysis chemistry.chemical_compound Colloid and Surface Chemistry Reaction rate constant chemistry Acetylene Carbon Lactone Equilibrium constant Palladium |
| Zdroj: | Journal of the American Chemical Society. 106:5505-5512 |
| ISSN: | 1520-5126 0002-7863 |
| DOI: | 10.1021/ja00331a019 |
| Popis: | Etude des reactions d'insertion intramoleculaires d'acetylene de ClL 2 PdCO 2 (CH 2 ) n C≡CCH 3 (n=2 L=Ph 3 P, n=2 L=p-tol 3 P, n=3 L=Ph 3 P) et de la reaction d'insertion intramoleculaire d'olefine de ClL 2 PdCO 2 CH 2 CH 2 CH=CH 2 (L=Ph 3 P) |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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