Quantum-chemical investigation of the mechanisms of reactions involving nucleophilic addition to acetylene. 2. Interconversions of products of the reaction of acetylene with the hydroxide ion

Autor:	O. Yu. Dolgunicheva, F. S. Dubnikova, Boris A. Trofimov, N. M. Vitkovskaya
Rok vydání:	1988
Předmět:	Quantum chemical chemistry.chemical_compound Nucleophilic addition Acetylene Chemistry Molecule Hydroxide General Chemistry Photochemistry Ion
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 37:1177-1180
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00961926
Popis:	1. According to the data form quantum-chemical calculations, the formation of vinyloxy anions from acetylene molecules and hydroxide ions occurs with the intermediate participation of [HC=CHOH]− anions (cis or trans), whose further conversion is possible only under fairly severe conditions. 2. The formation of the [H2C=COH]− anion according to the mechanisms considered is unlikely.
Databáze:	OpenAIRE
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