Variable‐Valent Rhenium Chemistry of Conjugated Nitrogenous Ligands: Structure and Reactivity

Autor:	Animesh Chakravorty
Rok vydání:	2005
Předmět:	Denticity Valence (chemistry) Ligand chemistry.chemical_element Rhenium Conjugated system Photochemistry Oxime Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art Polymer chemistry visual_art.visual_art_medium Diimine
Zdroj:	European Journal of Inorganic Chemistry. 2005:4863-4874
ISSN:	1099-0682 1434-1948
Popis:	The valence states of particular concern in this review are VI–I and the ligand types are diimine, azoimine, imineamide and azooximeall bidentate and N,N-coordinating. Metal reduction potentials and stability of oxidation states are subject to control via variation of the nature and extent of N,N-chelation and coligation. Back-bonding plays a major role in determining stability and isomer specificity, particularly in the valence domain III–I. Three types of mediated oxygen atom transfer processes have been scrutinized and modeled: from ReVO to tertiary phosphanes and variable-spacer diphosphanes, from water to diimine and from oxime to metal/coligand. Other reactivity topics include isomerizations associated with ligand substitution, stable azo anion radical generation and azo cleavage. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::212c65fe16d501872c6587015711fd99 https://doi.org/10.1002/ejic.200500615 Zobrazit plný text záznamu Plný text