Spin crossover and structural phase transition in homochiral and heterochiral Fe[(pybox)2]2+ complexes
| Autor: | Wan-Qing Gao, Chun-Hua Liu, Yin-Shan Meng, Tao Liu, Yuan-Yuan Zhu, Yao Pan |
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| Rok vydání: | 2019 |
| Předmět: |
Quantitative Biology::Biomolecules
Structural phase Materials science 010405 organic chemistry Spin transition Diastereomer 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Crystallography Molecular geometry Spin crossover Condensed Matter::Strongly Correlated Electrons Chirality (chemistry) |
| Zdroj: | Dalton Transactions. 48:6323-6327 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c8dt04893b |
| Popis: | Spin crossover and structural phase transition in three pairs of homochiral and heterochiral [Fe(pybox)2]2+ diastereomers were investigated through magnetic and crystallographic studies. Herein, we show that the spin transition properties of these compounds are strongly related to the homochiral or heterochiral assembly of the ligands and structural phase transition. Our work demonstrates that chirality is a feasible factor to modulate and influence the molecular geometry and thus the spin-crossover properties of complexes. |
| Databáze: | OpenAIRE |
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