Mg(OtBu)2-catalyzed C–H oxidation of α-azido arylethanones using TBHP as the oxidant and carbonyl oxygen source: facile access to primary α-ketoamides

Autor: Ying-Ying Peng, Bi-Yin Zhuo, Zhi-Qiang Wang, Bang Liu, Fu-Xing Zhang, Jiang-Xi Yu, Cheng-Yong Wang, Zhi-Feng Xu, Jin-Heng Li
Rok vydání: 2022
Předmět:
Zdroj: Organic Chemistry Frontiers. 9:5858-5863
ISSN: 2052-4129
DOI: 10.1039/d2qo01226j
Popis: A Mg(OtBu)2-catalyzed C(sp3)–H oxidation of α-azido arylethanones to straightforwardly produce primary α-ketoamides is presented.
Databáze: OpenAIRE