ChemInform Abstract: Samarium(II) Iodide-Promoted Reductive Fragmentation of γ-Halo Carbonyl Compounds: Application to the Enantiospecific Synthesis of (-) -Oudemansin A

Autor:	Koichi Naito, Toshio Honda, Yukio Suzuki, Shin-ichi Yamane
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Samarium chemistry.chemical_compound chemistry Fragmentation (mass spectrometry) Samarium(II) iodide Iodide Regioselectivity chemistry.chemical_element General Medicine Medicinal chemistry Oudemansin
Zdroj:	ChemInform. 23
ISSN:	0931-7597
DOI:	10.1002/chin.199249075
Popis:	The reductive regioselective bond-cleavage reaction of γ-halo carbonyl compounds with samarium(II) iodide is developed and its utilisation in the enantiospecific synthesis of (–)-oudemansin A is described.
Databáze:	OpenAIRE
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