A redox-active inorganic crown ether based on a polyoxometalate capsule

Autor: Nanako Tamai, Naoki Ogiwara, Eri Hayashi, Keigo Kamata, Toshiyuki Misawa, Takeru Ito, Tatsuhiro Kojima, Mireia Segado, Enric Petrus, Carles Bo, Sayaka Uchida
Rok vydání: 2023
Předmět:
Zdroj: Chemical Science. 14:5453-5459
ISSN: 2041-6539
2041-6520
DOI: 10.1039/d3sc01077e
Popis: The POM capsule functions as a redox-active inorganic crown ether. Specifically, Cs+ ions are captured in the crown-ether-like pores {Mo3Fe3O6}, which exist on the surface of the capsule, and electrons are stored in the Mo atoms of the capsule.
Databáze: OpenAIRE