Reductive Carbonylation of Oxorhenium Hydrides Induced by Lewis Acids
| Autor: | Roger D. Sommer, Cassandra P. Lilly, Leanna K. Robbins, Elon A. Ison, Nikola S. Lambic |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Sulfide 010405 organic chemistry Hydride Organic Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Adduct Inorganic Chemistry Metal Diamidopyridine chemistry visual_art visual_art.visual_art_medium Organic chemistry Chelation Lewis acids and bases Physical and Theoretical Chemistry Carbonylation |
| Zdroj: | Organometallics. 35:2822-2829 |
| ISSN: | 1520-6041 0276-7333 |
| Popis: | Several oxorhenium hydride complexes with chelating diamidopyridine (DAP), diamidoamine (DAAm), and 2-mercaptoethyl sulfide (SSS) groups have been isolated and characterized. Adduct formation is observed when the DAP complex 1a is treated with the Lewis acid B(C6F5)3. However, treatment of 1a,b with B(C6F5)3 or BF3·OEt2 in the presence of CO results in reduction of the metal center by four electrons from Re(V) to Re(I). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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