Structural and physical properties of a new reversible and continuous thermochromic ionic liquid in a wide temperature interval: [BMIM]4[Ni(NCS)6]
| Autor: | Carlos Fernández, Elena López Lago, Yago Arosa, Luisa Segade, Jacobo Troncoso, Esther Rilo, Bilal S. Algnamat, M. Pilar Vázquez-Tato, Jesús Rodríguez Fernández, Julio A. Seijas, Jesús Antonio Gonzalez, Luis M. Varela, Oscar Cabeza, Raúl de la Fuente, Imanol de Pedro |
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| Rok vydání: | 2018 |
| Předmět: |
Thermochromism
biology Analytical chemistry Liquid phase 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology biology.organism_classification 01 natural sciences Catalysis 0104 chemical sciences Paramagnetism chemistry.chemical_compound chemistry Ionic liquid Materials Chemistry Tetra 0210 nano-technology |
| Zdroj: | New Journal of Chemistry. 42:15561-15571 |
| ISSN: | 1369-9261 1144-0546 |
| Popis: | We report spectroscopic, structural, optical and magnetic characterization of tetra(1-butyl-3-methylimidazolium)hexaisothiocyanatonickelate. This paramagnetic ionic liquid exhibits reversible and continuous thermochromism from 298 K up to 400 K and it is solar responsive resisting numerous heating–cooling cycles. Its appearance changes from pale blue to grass green from 298 K to 343 K. Well above these temperatures it becomes brown and gray. Thermochromism is observed both in the solid and liquid phase. |
| Databáze: | OpenAIRE |
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