Conjugation and hydrogen bonding in a curcumin analogue

Autor:	Kjersti Ann Haglund, Arvid Mostad, Antonio F. Arrieta
Rok vydání:	2000
Předmět:	chemistry.chemical_compound chemistry Group (periodic table) Stereochemistry Hydrogen bond Atom Curcumin Moiety General Medicine Crystal structure Medicinal chemistry Enol General Biochemistry Genetics and Molecular Biology
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 56:e594-e595
ISSN:	0108-2701
DOI:	10.1107/s0108270100015729
Popis:	The strongly yellow-coloured compound 5-(5-methyl-2,3,4,5-tetra­hydro­furan-2-yl)-1-phenyl­pent-4-ene-1,3-dione, C16H14O3, has different substituents on each side of the dione group. The mol­ecule is essentially planar and the structure indicates a continuous conjugation from the furyl moiety to the carbonyl O atom in the enol group, as well as a strong conjugation within the enol group itself. The enol H atom is bonded to the O atom closest to the furyl group. Weak hydrogen bonds are indicated and comments about the colour of the compound are given.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::20d43a7facd1ee411eb69f8a5c5a4b52 https://doi.org/10.1107/s0108270100015729 Zobrazit plný text záznamu Plný text