Antimony Film Microelectrode for Anodic Stripping Measurement of Cadmium(II), Lead(II) and Copper(II)

Autor:	Ivan Švancara, Samo B. Hočevar, Bozidar Ogorevc, Lucie Baldrianova, Eva Tesarova, Marija Slavec, Karel Vytras
Rok vydání:	2010
Předmět:	Microelectrode Anodic stripping voltammetry Cadmium chemistry Stripping (chemistry) Antimony Metal ions in aqueous solution Inorganic chemistry Electrochemistry chemistry.chemical_element Copper Analytical Chemistry Anode
Zdroj:	Electroanalysis. 22:1617-1622
ISSN:	1521-4109 1040-0397
Popis:	The antimony film microelectrode (SbFME) is presented for measuring trace heavy metal ions in combination with anodic stripping voltammetry. The SbFME was tested in model solutions of 0.01 M HCl containing Cd(II) and Pb(II) in the presence of dissolved oxygen. The microsensor exhibited good linear behavior in the examined concentration range 20 μg L−1 to 100 μg L−1 and LoD of 1.9 and 3.1 μg L−1 for Cd(II) and Pb(II), respectively. The suitability of SbFME for measuring trace levels of Cu(II) was demonstrated using the standard reference material of natural water exploiting the sensor's specific characteristic of low re-oxidation signal for antimony.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::209e26016e260d307752f70f325c9284 https://doi.org/10.1002/elan.200900583 Zobrazit plný text záznamu Plný text