ChemInform Abstract: Synthesis of Cyclic Metal-Containing Phosphorus-Nitrogen Compounds - A Comparison with Metal-Containing Siloxanes

Autor:	Norbert Winkhofer, Herbert W. Roesky, Feng Quan Liu, Mathias Noltemeyer, R. Hasselbring, P. Olms
Rok vydání:	2010
Předmět:	010405 organic chemistry Phosphorus Inorganic chemistry chemistry.chemical_element General Medicine 010402 general chemistry 01 natural sciences Nitrogen 0104 chemical sciences Metal chemistry Polymerization visual_art visual_art.visual_art_medium
Zdroj:	ChemInform. 24
ISSN:	0931-7597
DOI:	10.1002/chin.199335262
Popis:	The preparation and properties of six- and higher- membered metallacyclophosphazenes is described. A new mechanism for the polymerisation of cyclophosphazenes is discussed. The PN unit is isoelectronic to the SIO unit and therefore metal containing siloxanes have been prepared. They function as model compounds for metal oxides on silica surfaces.
Databáze:	OpenAIRE
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